Yadav, J. S. ; Subba Reddy, B. V. ; Padmavani, B. ; Venugopal, Ch. ; Bhaskar Rao , A. (2007) Enzymatic kinetic resolution of racemic 4-tetrahydropyranols by Candida rugosa lipase Tetrahedron Letters, 48 (26). pp. 4631-4633. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.04.091
Abstract
Enzymatic kinetic resolution of (±)-hydroxytetrahydropyrans has been achieved for the first time by means of lipase-mediated transesterification to afford optically active (2S,4R)-tetrahydropyranyl acetates and (2R,4S)-tetrahydropyranols in excellent yields with high enantioselectivity. Absolute configurations of the tetrahydropyranyl acetates were assigned as (S) by chemical correlation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Kinetic Resolution; Lipase; Tetrahydropyranols |
| ID Code: | 58775 |
| Deposited On: | 02 Sep 2011 03:26 |
| Last Modified: | 02 Sep 2011 03:26 |
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