Yadav, J. S. ; Reddy, B. V. S. ; Murali Krishna Reddy, P. ; Gupta, Manoj K. (2005) Zn/[bmim]PF6-mediated Markovnikov allylation of unactivated terminal alkynes Tetrahedron Letters, 46 (48). pp. 8411-8413. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.09.147
Abstract
A simple and highly regioselective method has been developed for the allylation of unactivated terminal alkynes with allyl bromide using Zn/[bmim]PF6 as an inexpensive, readily available and recyclable reagent system. High conversions and enhanced selectivity together with the environmentally benign nature of the Zn/[bmim]PF6 reagent system makes this method an attractive alternative to established methods.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Terminal Alkynes; Zinc; Allyl Bromide; Ionic Liquids |
| ID Code: | 58763 |
| Deposited On: | 02 Sep 2011 03:21 |
| Last Modified: | 02 Sep 2011 03:21 |
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