In(OTf)3-catalyzed synthesis of 4-thiocyanotetrahydropyrans via a three-component reaction

Yadav, J. S. ; Subba Reddy, B. V. ; Maity, Tapas ; Narayana Kumar, G. G. K. S. (2007) In(OTf)3-catalyzed synthesis of 4-thiocyanotetrahydropyrans via a three-component reaction Tetrahedron Letters, 48 (50). pp. 8874-8877. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.10.047

Abstract

A three-component coupling of aldehydes, homoallylic alcohols and ammonium thiocyanate is achieved in the presence of 10 mol % of In(OTf)3 in refluxing dichloromethane to produce 4-thiocyanotetrahydropyrans in excellent yields with all cis-selectivity. This method is simple, selective and convenient for introducing an SCN group onto a tetrahydropyran ring.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Prins-cyclization; Three-component Reaction; 4-thiocyanotetrahydropyrans
ID Code:58751
Deposited On:02 Sep 2011 03:29
Last Modified:02 Sep 2011 03:29

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