GaCl3-catalyzed addition of thiols to glycals: a facile synthesis of 2-deoxy thioglycosides

Yadav, J. S. ; Subba Reddy, B. V. ; Vijaya Bhasker, E. ; Raghavendra, S. ; Narsaiah, A. V. (2007) GaCl3-catalyzed addition of thiols to glycals: a facile synthesis of 2-deoxy thioglycosides Tetrahedron Letters, 48 (4). pp. 677-680. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.11.103

Abstract

Gallium(III) chloride catalyzes efficiently the addition of thiols to glycals under extremely mild conditions to afford 2-deoxy thioglycosides in high yields with a good α-selectivity. The reactions proceed rapidly at ambient temperature.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Glycals; Thiols; Gallium(III) Halide; 2-deoxy Sugars; Thioglycosides
ID Code:58749
Deposited On:02 Sep 2011 03:24
Last Modified:02 Sep 2011 03:24

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