Taqui Khan, M. M. ; Mehta, S. H. ; Prakash Rao, A. ; Bhatt, K. N. (1992) Electrocatalytic oxidation of organic substrates with oxygen using ruthenium-Schiff base complex Journal of Molecular Catalysis, 75 (3). pp. 245-251. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(92)80129-5
Abstract
Electrochemical behaviour of the ruthenium(III)-Schiff base complex [RuIII(Naphdien)Cl] 1 (Naphdien=bis(2-hydroxynaphthaldehyde)diethylenetriaminato) was studied in the presence of benzoic anhydride, dioxygen, tetrabutylammonium perchlorate (TBAP) and organic substrates. Cyclic voltammetric findings confirm an 'ECE' pathway for the studied reactions. Controlled potential electrolysis experiments with cyclohexene, cyclooctene and triphenylphosphine at -0.24 V (vs. SCE) yielded primarily cyclohexene oxide, cyclooctene oxide and triphenylphosphine oxide with turnover rates of 2.3, 2.6 and 5.4 moles of product per mole catalyst per hour, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58552 |
| Deposited On: | 31 Aug 2011 12:23 |
| Last Modified: | 31 Aug 2011 12:23 |
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