Taqui Khan, M. M. ; Sreelatha, Ch. ; Mirza, Shaukat A. ; Ramachandraiah, G. ; Abdi, S. H. R. (1988) Synthesis and characterization of some ruthenium(V) oxo complexes of the Schiff base, bis(salicylaldehyde)-o-phenylenediamine, with appended Cl−, imidazole and 2-methylimidazole: the first examples of stable oxo complexes via direct oxygenation Inorganica Chimica Acta, 154 (1). pp. 103-108. ISSN 0020-1693
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0020-1693(00)85173-7
Abstract
Oxygenation of ruthenium(III) Schiff base complexes of the composition K[RuIII(Saloph)Cl2] and [RuIII(Saloph)XCl] (Saloph=bis(salicylaldehyde)-o- phenylenediamine; X=imidazole (Im), 2-methylimidazole (2-MeIm)) with molecular oxygen gives the oxo derivatives of the composition, [RuV(Saloph)X- (O)]+ (X=Cl, Im or 2-MeIm). The oxo complexes were also synthesized by the reaction of [RuIII- (Saloph)XCl] with PhIO or H2O2. The complexes thus obtained were characterized by analytical data, molar conductance, magnetic susceptibility, spectroscopic and electrochemical methods. Kinetics of the oxygenation reaction have also been investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58511 |
| Deposited On: | 31 Aug 2011 12:16 |
| Last Modified: | 31 Aug 2011 12:16 |
Repository Staff Only: item control page
