Taqui Khan, M. M. ; Halligudi, S. B. ; Abdi, S. H. R. (1988) An efficient water-soluble ruthenium hydroformylation catalyst for the exclusive formation of 1-heptaldehyde from 1-hexene Journal of Molecular Catalysis, 48 (2-3). pp. 313-317. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(88)85013-2
Abstract
Hydroformylation of 1-hexene was carried out in a high pressure reactor using water soluble [Ru(III)-EDTA] catalyst, synthesis gas (1:1) CO + H2 at 50 atm, in 80:20 ethanol-water mixture and at 130°C. The reaction proceeds with a turnover rate of 11.83 mol product per mol catalyst per hour with the conversion of 1-hexene exclusively (100%) to linear 1-heptaldehyde.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58509 |
| Deposited On: | 31 Aug 2011 12:16 |
| Last Modified: | 31 Aug 2011 12:16 |
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