Synthesis of the complex [RuV=O(edta)] and its application in the oxidation of saturated substrates by oxygen atom transfer reaction

Taqui Khan, M. M. ; Chatterjee, Debabrata ; Merchant, R. R. ; Bhatt, Anjani ; Sanal, Kumar S. (1991) Synthesis of the complex [RuV=O(edta)] and its application in the oxidation of saturated substrates by oxygen atom transfer reaction Journal of Molecular Catalysis, 66 (3). pp. 289-293. ISSN 0304-5102

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0304-5102(91)80021-T

Abstract

Oxidation of cyclohexane and cyclohexanol with Ru(edta)(O) was studied spectrophotometrically by following the disappearance of the oxo peak of the complex RuV(edta)(O) at constant pH 5.0. The reaction rate was found to be first order with respect to oxo complex. The rate of oxidation increases with increasing substrate concentration and reaches a limit at high substrate concentration. Rate and activation parameters are in accordance with the mechanism proposed for the oxygen atom transfer reaction from high-valent RuV(edta)(O) complexes to saturated hydrocarbons.

Item Type:Article
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ID Code:58504
Deposited On:31 Aug 2011 12:21
Last Modified:31 Aug 2011 12:21

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