Taqui Khan, M. M. ; Hussain, Amjad ; Moiz, M. A. (1992) Reaction of CO with K[Ru(EDTAH)HO]: formation of stable ruthenium(III) carbonyl comReaction of CO with K[Ru(EDTAH)H2O]: formation of stable ruthenium(III) carbonyl complexesplexes Polyhedron, 11 (6). pp. 687-689. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)83326-4
Abstract
Interaction of K[Ru(EDTAH)Cl] (1) with CO at very low pH (1.0) produces the protonated species [Ru(EDTAH)(CO)(H2O)] (2). Interaction of 1 with CO results in the formation of K[Ru(EDTA)(CO)H2O] (3) and K3[(Ru(EDTA))2-μ-CO-μ-OH] (4). Complexes 2 and 3 have a μeff of 1.90 and 1.87 B.M., respectively, while complex 4 exhibits a μeff of 3.97 B.M. The EPR of complex 4 shows a resonance at half field position at 4.60 as a result of RuIII-RuIII coupling.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58503 |
| Deposited On: | 31 Aug 2011 12:22 |
| Last Modified: | 31 Aug 2011 12:22 |
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