Epoxidation of cyclohexene with iodosylbenzene catalysed by Ru(III)-dmg and Ru(III)-dpg complexes: synthesis and characterisation of catalytically active Ru(V)-oxo intermediates

Taqui Khan, M. M. ; Chatterjee, Debabrata ; Khan, N. H. ; Kureshi, R. I. ; Bhatt, K. N. (1992) Epoxidation of cyclohexene with iodosylbenzene catalysed by Ru(III)-dmg and Ru(III)-dpg complexes: synthesis and characterisation of catalytically active Ru(V)-oxo intermediates Journal of Molecular Catalysis, 77 (2). pp. 153-158. ISSN 0304-5102

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0304-5102(92)80195-M

Abstract

The complexes K[RuIII(H-dmg)2Cl2], 1 (dmg= dimethylglyoxime), and K[RuIII(H-dpg)2Cl2], 2 (dpg=diphenylglyoxime), and the oxo complexes [Ruv(H-dmg)2(O)Cl], 3, and [Ruv(H-dpg)2(O)Cl], 4, were synthesised and characterised by elemental analysis, UV-Vis and IR spectroscopy and electrochemical studies. The epoxidation of cyclohexene with iodosylbenzene catalysed by complexes 1 and 2 is reported.

Item Type:Article
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ID Code:58495
Deposited On:31 Aug 2011 12:23
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