Methanol-to-gasoline(MTG)conversion over ZSM-5. A temperature programmed surface reaction study

Abstract

The conversion of methanol to gasoline over zeolite ZSM-5 has been studied by temperature programmed surface reaction (TPSR). The technique is able to monitor the two steps in the process: the dehydration of methanol to dimethyl ether and the subsequent conversion of dimethyl ether to hydrocarbons. The activation barriers associated with each step were evaluated from the TPSR profiles and are 25.7 and 46.5 kcal/mol respectively. The methanol desorption profile shows considerable change with the amount of methanol molecules adsorbed per Brønsted site of the zeolite. The energy associated with the desorption process, (CH₃OH)_nH⁺-ZSM5 → (CH₃OH)_n-1H⁺-ZSM5+CH₃OH, shows a spectrum of values depending on n.