Mohanambe, L. ; Vasudevan, S. (2005) Inclusion of ferrocene in a cyclodextrin-functionalized layered metal hydroxide: a new organometallic-organic-LDH nanohybrid Inorganic Chemistry, 44 (7). pp. 2128-2130. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic050039a
Related URL: http://dx.doi.org/10.1021/ic050039a
Abstract
Cyclodextrin cavities have been grafted into a layered metal hydroxide to create hydrophobic nanopockets within the galleries of the inorganic solid. Neutral ferrocene molecules can be included within the grafted cavities by partitioning from a polar solvent to generate a new organometallic-organic-inorganic hybrid. The included ferrocene has been characterized by electronic and Raman spectroscopy. The capability of the cyclodextrin-functionalized solid to separate hydrophobic and hydrophilic derivatives of ferrocene is demonstrated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 58459 |
| Deposited On: | 31 Aug 2011 06:06 |
| Last Modified: | 31 Aug 2011 06:06 |
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