Palladium catalysed reactions of Baylis-Hillman products: synthesis of some useful intermediates

Kumareswaran, R. ; Vankar, Yashwant D. (1998) Palladium catalysed reactions of Baylis-Hillman products: synthesis of some useful intermediates Synthetic Communications, 28 (12). pp. 2291-2302. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919808007047

Abstract

Acetates derived from Baylis-Hillman products were reacted with sodio dimethyl (or diethyl) malonate under Pd(0) catalysis to form E olefins as the major products. Likewise, the Heck reaction with these acetates as well as with the corresponding alcohols form a variety of useful intermediates which include trisubstituted olefinic compounds and α-benzyl β-keto esters.

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