A convenient synthesis of vinyl epoxides from glycidic esters via α-hydroxy-β,γ-unsaturated esters

Bhattacharya, Indrani ; Shah, Kavita ; Vankar, Padma S. ; Vankar, Yashwant D. (1993) A convenient synthesis of vinyl epoxides from glycidic esters via α-hydroxy-β,γ-unsaturated esters Synthetic Communications, 23 (17). pp. 2405-2414. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919308011126

Abstract

Glycidic esters, upon isomerisation with BF3.Et2O yield α-hydroxy-β,γ-unsaturated esters. These are then reduced with LiAlH4 to vicinal diols which are converted to vinyl epoxides in two steps.

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Deposited On:31 Aug 2011 06:34
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