John Pal, A. P. ; Mallick, Asadulla ; Suman Reddy, Y. ; Vankar, Yashwant D. (2010) Molecular iodine-promoted N- and C-glycosylation of 1-C-alkyl (or phenyl)-glycopyranoses Tetrahedron Letters, 51 (48). pp. 6334-6337. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.09.124
Abstract
Molecular iodine efficiently promoted the N- and C-glycosylation of hemiketals with Me3SiN3 and Me3SiCN, respectively. Using this method we have prepared diverse functional N- and C-ketosides, which could serve as useful synthons for the preparation of unnatural glycosyl amino acids or glycopeptides.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Molecular Iodine; Ketoses; Glycosylation; N-Ketosides; C-Ketosides |
ID Code: | 58299 |
Deposited On: | 31 Aug 2011 06:42 |
Last Modified: | 31 Aug 2011 06:42 |
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