Vankar, Padma S. ; Bhattacharya, Indrani ; Vankar, Yashwant D. (1996) Asymmetric synthesis of chiral vinylic epoxides and α-hydroxy-β,γ-unsaturated esters via (-)-menthol based auxiliary and enzymatic resolution respectively Tetrahedron: Asymmetry, 7 (6). pp. 1683-1694. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0957-4166(96)00202-9
Abstract
Using (-)-menthol as an auxiliary, three chiral vinylic epoxides have been synthesised from the corresponding glycidic esters via α-hydroxy-β,γ-unsaturated esters. Enzymatic resolution of α-acetoxy-β,γ-unsaturated esters using PLAP leads to optically active α-hydroxy- β,γ-unsaturated esters.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58295 |
| Deposited On: | 31 Aug 2011 06:35 |
| Last Modified: | 31 Aug 2011 06:35 |
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