Synthetic methods are reactions. 73. Conversion of epoxides and enamines into α-haloketones with halodimethylsulfonium halides

Olah, George A. ; Vankar, Yashwant D. ; Arvanaghi, Massoud (1979) Synthetic methods are reactions. 73. Conversion of epoxides and enamines into α-haloketones with halodimethylsulfonium halides Tetrahedron Letters, 20 (38). pp. 3653-3656. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)95488-7

Abstract

Epoxides, upon treatment with halodimethylsulfonium halides in the presence of triethylamine are converted in high yield into α-haloketones. Enamines similarly react with bromodimethylsulfonium bromide to give α-bromoketones.

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ID Code:58287
Deposited On:31 Aug 2011 06:27
Last Modified:31 Aug 2011 06:27

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