Yadav, Veejendra K. ; Ganesh Babu, K. ; Parvez, Masood (2004) Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation Journal of Organic Chemistry, 69 (11). pp. 3866-3874. ISSN 0022-3263
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/jo034608c
Related URL: http://dx.doi.org/10.1021/jo034608c
Abstract
The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising from the substituents on the sulfur atom and the γ-carbon and the bulk of the nucleophile constitute the major control elements.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 58254 |
| Deposited On: | 31 Aug 2011 06:56 |
| Last Modified: | 31 Aug 2011 06:56 |
Repository Staff Only: item control page
