Yadav, Veejendra K. ; Ganesh Babu, K. ; Mittal, Manish (2001) KF-Al2O3 is an efficient solid support reagent for the acetylation of amines, alcohols, and phenols. Impeding effect of solvent on the reaction rate Tetrahedron, 57 (32). pp. 7047-7051. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)00677-9
Abstract
KF-Al2O3 brings about rapid acetylation of a range of amines, alcohols, and phenols with Ac2O/AcCl. Aliphatic alcohols are acetylated chemoselectively in the presence of phenols. 1° alcohols react several times faster than 2° alcohols. 3° alcohols do not react.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | KF-AL2O3; Acetylation; Chemoselectivity; Solvent Effect |
| ID Code: | 58207 |
| Deposited On: | 31 Aug 2011 06:53 |
| Last Modified: | 31 Aug 2011 06:53 |
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