Vankar, Yashwant D. ; Chaudhuri, Narayan C. ; Trinadha Rao, C. (1987) Regioselective reductions of 2,3-epoxy acetals with zinc-chlorotrimethylsilane and lithium aluminium hydride: convenient synthesis of 1,2 and 1,3-diones Tetrahedron Letters, 28 (5). pp. 551-554. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)95779-4
Abstract
A variety of 2,3-epoxy acetals have been found to undergo regioselective reductions with zinc-chlorotrimethylsilane and lithium aluminium hydride to give 2-hydroxy and 3-hydroxy acetals respectively. Their oxidation followed by hydrolysis furnished the corresponding 1,2- and 1,3-diones in good yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58201 |
| Deposited On: | 31 Aug 2011 06:33 |
| Last Modified: | 31 Aug 2011 06:33 |
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