Vankar, Yashwant D. ; Bava, Anita ; Kumaravel, G. (1991) Reaction of 2-nitro and 3-nitro-2-cyclohexenone acetals: preparation of useful intermediates Tetrahedron, 47 (10-11). pp. 2027-2040. ISSN 0040-4020
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)96113-7
Abstract
Preparation of 2-nitro-2-cyclohexenone acetal 31̅ starting from 2-nitrocyclohexanone acetal 29̅ has been reported for the first time. This compound as well as 3-nitro-2-cyclohexenone acetal 1̅, whose synthesis has been reported by us earlier, react with a variety of nucleophiles to form highly functionalised intermediates. One of them viz. 21̅ is converted into a bicyclic α- methylenen-γ-lactone 24̅ using radical chemistry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58200 |
| Deposited On: | 31 Aug 2011 06:34 |
| Last Modified: | 31 Aug 2011 06:34 |
Repository Staff Only: item control page
