Vankar, Yashwant D. ; Venkatram Reddy, M. ; Chaudhuri, Narayan C. (1994) Chiral acetals in organic synthesis: regioselective synthesis of 2-and 3-hydroxy acetals from 2,3-olefinic acetals. Reinvestigation and further applications Tetrahedron, 50 (37). pp. 11057-11078. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)85714-8
Abstract
Achiral as well as chiral 2,3-olefinic acetals are converted into 2- and 3- hydroxy acetals via LAH reduction of the corresponding epoxides and via bromohydrins followed by TBTH reductions respectively. Synthesis of 1,3-diones is described. Compounds from chiral systems are further utilized for asymmetric synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58197 |
| Deposited On: | 31 Aug 2011 06:35 |
| Last Modified: | 31 Aug 2011 06:35 |
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