Kumar, Amit ; Alam, Mohammed Abrar ; Rani, Shikha ; Vankar, Yashwant D. (2010) Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from D-xylose Carbohydrate Research, 345 (9). pp. 1142-1148. ISSN 0008-6215
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.carres.2010.04.016
Abstract
The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iminosugars; Lactol; Wittig Olefination; Ring Closing Metathesis; Dihydroxylation; D-Xylose |
| ID Code: | 58188 |
| Deposited On: | 31 Aug 2011 06:42 |
| Last Modified: | 31 Aug 2011 06:42 |
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