Kokatla, Hari Prasad ; Lahiri, Rima ; Kancharla, Pavan K. ; Doddi, Venkata Ramana ; Vankar, Yashwant D. (2010) Synthesis of (−)-deoxoprosophylline, (+)-2-epi-deoxoprosopinine, and (2R,3R)- and (2R,3S)-3-hydroxypipecolic acids from D-glycals Journal of Organic Chemistry, 75 (13). pp. 4608-4611. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo100489k
Related URL: http://dx.doi.org/10.1021/jo100489k
Abstract
New syntheses of (−)-deoxoprosophylline, (+)-2-epi-deoxoprosopinine, and (2R,3R)- and (2R,3S)-3-hydroxypipecolic acids are reported. Utilization of the chiral functionalities of Perlin aldehydes, derived from 3,4,6-tri-O-benzyl glycals, has been done along with chemoselective saturation of olefins and reductive aminations as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 58183 |
| Deposited On: | 31 Aug 2011 06:42 |
| Last Modified: | 31 Aug 2011 06:42 |
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