Novel nucleophilic heterocyclic carbene mediated stereoselective conjugate addition of enals to nitrostyrenes via homoenolate

Nair, Vijay ; Sinu, C. R. ; Babu, Beneesh P. ; Varghese, Vimal ; Jose, Anu ; Suresh, Eringathodi (2009) Novel nucleophilic heterocyclic carbene mediated stereoselective conjugate addition of enals to nitrostyrenes via homoenolate Organic Letters, 11 (24). pp. 5570-5573. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol901918x

Related URL: http://dx.doi.org/10.1021/ol901918x

Abstract

A stereoselective Michael addition of homoenolate, generated from enals by nucleophilic heterocyclic carbene (NHC) catalysis, to β-nitrostyrenes is reported for the first time. The products of this reaction obtained in good yields are of potential value in the synthesis of a variety of acyclic and heterocyclic compounds.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:58061
Deposited On:31 Aug 2011 12:49
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