Chemoselective 1, 3-dipolar cycloaddition reactions of rhodium (II)-generated isomünchnones with 1, 4-quinones: synthesis of novel azapolycycles

Nair, Vijay ; Santhi, V. ; Sheela, K. C. ; Radhakrishnan, K. V. ; Rath, Nigam P. (2003) Chemoselective 1, 3-dipolar cycloaddition reactions of rhodium (II)-generated isomünchnones with 1, 4-quinones: synthesis of novel azapolycycles Synthesis, 2003 (10). pp. 1559-1564. ISSN 0039-7881

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2003-40529

Abstract

The formation of the hybrid skeletons of oxoprotoberberines and quinonoid natural products is achieved by the cycloaddition of isomünchnones with 1,4-quinones, followed by BF3·OEt2-catalyzed transformation of the adducts.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Hybrid Compounds; Oxoprotoberberines; Isomünchnones; 1,4-quinones; Cycloaddition
ID Code:58059
Deposited On:31 Aug 2011 12:45
Last Modified:31 Aug 2011 12:45

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