Stereoselective synthesis of spirocyclopentanones via N-heterocyclic carbene-catalyzed reactions of enals and dienones

Nair, Vijay ; Babu, Beneesh Pattoorpadi ; Vellalath, Sreekumar ; Suresh, Eringathodi (2008) Stereoselective synthesis of spirocyclopentanones via N-heterocyclic carbene-catalyzed reactions of enals and dienones Chemical Communications (6). pp. 747-749. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2008...

Related URL: http://dx.doi.org/10.1039/B715733A

Abstract

Homoenolates generated from enals by nucleophilic heterocyclic carbene (NHC) catalysis undergo a conjugate addition/cyclization sequence with cyclic dienones, culminating in the efficient synthesis of spirocyclopentanones.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:58053
Deposited On:31 Aug 2011 12:49
Last Modified:31 Aug 2011 12:49

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