Taqui Khan, M. M. ; Prakash Rao, A. (1987) Oxygen atom transfer in the epoxidation of cyclohexene catalysed by Ru(III)-EDTA Journal of Molecular Catalysis, 39 (3). pp. 331-340. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(87)80078-0
Abstract
The oxidation of cyclohexene to the epoxide is catalysed by Ru(III)-EDTA in a 50% ethanol/water solution at 30°C in the pH range 1-3 (μ=0.1 M KCl). The observed reaction rates for the oxidation of cyclohexene are first order with respect to Ru(III)-EDTA and cyclohexene, and one-half order with respect to molecular oxygen. A mechanism has been proposed for the oxidation of cyclohexene by molecular oxygen catalysed by Ru(III)-EDTA. The turnover number for the epoxidation of cyclohexene by molecular oxygen catalysed by Ru(III)-EDTA is 200 mol (mol catalyst) −1min−1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 57842 |
| Deposited On: | 30 Aug 2011 10:27 |
| Last Modified: | 30 Aug 2011 10:27 |
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