Taqui Khan, M. M. ; Halligudi, S. B. ; Abdi, S. H. R. (1988) Hydroformylation of allyl alcohol catalyzed by water-soluble Ru(III)-EDTA complex Journal of Molecular Catalysis, 45 (2). pp. 215-224. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(88)80011-7
Abstract
Hydroformylation of allyl alcohol was studied in aqueous medium using [Ru(III)-EDTA] complex as catalyst and (1:1) CO + H2 gas in a high pressure autoclave at pressures up to 50 atm and in the temperature range 90-130°C. The hydroformylation of allyl alcohol gives γ-hydroxybutyraldehyde as the primary product, along with the side products γ-butyrolactone, dihydrofuran and 1,4-butanediol. The hydroformylation of allyl alcohol is first order with respect to allyl alcohol and catalyst concentrations, and has a linear dependence on CO + H2 (1:1) pressure of the syngas. The activation energy of the reaction is found to be 23.13 kcal mol−1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 57841 |
| Deposited On: | 30 Aug 2011 10:28 |
| Last Modified: | 30 Aug 2011 10:28 |
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