Taqui Khan, M. M. ; Chatterjee, Debabrata ; Bajaj, H. C. (1993) Selective oxidation of cyclohexane by a Ru(III) analogue of the gif-system. RuIII acetic acid-pyridine-KHSO5 Reaction Kinetics and Catalysis Letters, 49 (1). pp. 81-85. ISSN 0133-1736
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Official URL: http://www.springerlink.com/content/h2u37x73764170...
Related URL: http://dx.doi.org/10.1007/BF02084032
Abstract
Selective oxidation of cyclohexane to cyclohexanone was carried out in a RuCl3-pyridine-acetic acid-KHSO5 mixture. This system yields 2.8% of cyclohexanone (based on 'oxone' concentration) under the conditions employed. Mechanistic postulate for the oxidation reaction involves the formation of a carbene intermediate (Ru=C) prior to the ketone formation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 57806 |
| Deposited On: | 30 Aug 2011 10:32 |
| Last Modified: | 30 Aug 2011 10:32 |
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