Taqui Khan, M. M. ; Khan, Badar Taqui ; Begum, Safia (1987) Kinetics of homogeneous hydrogenation of 1-pentene catalysed by bis(diphenylphosphinoethylamine) chlororhodium (I) Reaction Kinetics and Catalysis Letters, 34 (1). pp. 105-111. ISSN 0133-1736
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Official URL: http://www.springerlink.com/content/mmw3w257556864...
Related URL: http://dx.doi.org/10.1007/BF02069209
Abstract
Catalytic homogeneous hydrogenation of 1-pentene catalyzed by bis(diphenylphosphinoethylamine) chlororhodium(I) [RhClHN(CH2CH2PPh2)2](1̲) was investigated over the temperature range 10-20°C under 1 atm of hydrogen pressure. The dependence of the rate of hydrogenation on temperature, catalyst and substrate concentration in solution is reported. The thermodynamic and activation parameters for the hydrogenation of 1-pentene catalyzed by 1̲ were computed and compared with those of cyclohexene and 1-heptene.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 57801 |
| Deposited On: | 30 Aug 2011 10:26 |
| Last Modified: | 30 Aug 2011 10:26 |
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