Taqui Khan, M. M. ; Khan, Badar T. ; Safia, (1985) Kinetics of homogeneous hydrogenation of cyclohexene catalyzed by complexes of rhodium and iridium with a terdentate ligand Reaction Kinetics and Catalysis Letters, 29 (1). pp. 63-70. ISSN 0133-1736
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Official URL: http://www.springerlink.com/content/p614816r6w44j2...
Related URL: http://dx.doi.org/10.1007/BF02067950
Abstract
Complexes of the composition MC1HN (CH2CH2AsPh2)2 (M= =Rh(I), Ir(I) were used as catalysts for the homogeneous hydrogenation of cyclohexene over the temperature range 20-50°C and 0.4 to 1 atm hydrogen partial pressure. The dependence of rate of hydrogenation on temperature, hydrogen concentration, catalyst concentration and substrate concentration is reported. The activation parameters of the reaction, ΔH∗ and ΔS∗ have been evaluated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 57798 |
| Deposited On: | 30 Aug 2011 10:25 |
| Last Modified: | 30 Aug 2011 10:25 |
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