Self-assembled molecular films of tetraamino metal (Co, Cu, Fe) phthalocyanines on gold and silver: electrochemical and spectroscopic characterization

Somashekarappa, M. P. ; Keshavayya, J. ; Sampath, S. (2002) Self-assembled molecular films of tetraamino metal (Co, Cu, Fe) phthalocyanines on gold and silver: electrochemical and spectroscopic characterization Pure and Applied Chemistry, 74 (9). pp. 1609-1620. ISSN 0033-4545

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Official URL: http://www.iupac.org/publications/pac/74/9/1609/

Related URL: http://dx.doi.org/10.1351/pac200274091609

Abstract

The formation of molecular films of 2,9,16,23-tetraamino metal phthalocyanines [TAM(II)Pc; M (II) = Co, Cu, and TAM(III)Pc; M = Fe] by spontaneous adsorption on gold and silver surfaces is described. The properties of these films have been investigated by cyclic voltammetry, impedance, and FT-Raman spectroscopy. The charge associated with Co(II) and Co(I) redox couple in voltammetric data leads to a coverage of (0.35 ± 0.05) × 10-10 mol cm-2, suggesting that the tetraamino cobalt phthalocyanine is adsorbed as a monolayer with an almost complete coverage. The blocking behavior of the films toward oxygen and Fe(CN)6 3-/4- redox couple have been followed by cyclic voltammetry and impedance measurements. This leads to an estimate of the coverage of about 85 % in the case of copper and the iron analogs. FT-Raman studies show characteristic bands around 236 cm-1 revealing the interaction between the metal substrate and the nitrogen of the -NH2 group on the phthalocyanine molecules.

Item Type:Article
Source:Copyright of this article belongs to International Union of Pure and Applied Chemistry.
ID Code:57335
Deposited On:26 Aug 2011 08:14
Last Modified:26 Aug 2011 08:14

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