Suppression of spin-spin coupling in nitroxyl biradicals by supramolecular host-guest interactions

Porel, Mintu ; Ottaviani, M. Francesca ; Jockusch, Steffen ; Jayaraj, Nithyanandhan ; Turro, Nicholas J. ; Ramamurthy, V. (2010) Suppression of spin-spin coupling in nitroxyl biradicals by supramolecular host-guest interactions Chemical Communications, 46 (41). pp. 7736-7738. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2010...

Related URL: http://dx.doi.org/10.1039/C0CC02587A, Communication

Abstract

The use of supramolecular architectures to control the spatially dependent spin exchange (spin communication) between two covalently linked radical centers (biradical) has been explored. Cucurbit[8]uril, through supramolecular steric effect, completely suppresses spin exchange between two adjacent radical centers in a biradical.

Item Type:Article
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ID Code:55876
Deposited On:19 Aug 2011 07:51
Last Modified:19 Aug 2011 07:51

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