Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state

Natarajan, Arunkumar ; Mague, Joel T ; Venkatesan, K. ; Arai, T. ; Ramamurthy, V. (2006) Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state Journal of Organic Chemistry, 71 (3). pp. 1055-1059. ISSN 0022-3263

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0520644

Related URL: http://dx.doi.org/10.1021/jo0520644

Abstract

Volume-demanding cis-trans photoisomerization of the aromatic substituted alkenes 1-3 in the solid state at room temperature and at 50 °C is presented. Alkene 3 did not undergo the cis-trans isomerization in the solid state either at room temperature or at 50 °C. The importance of the presence of void space near the reaction center to facilitate the large volume change during cis-trans photoisomerization is discussed.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:55860
Deposited On:19 Aug 2011 07:49
Last Modified:16 Jul 2012 15:31

Repository Staff Only: item control page