Natarajan, Arunkumar ; Mague, Joel T ; Venkatesan, K. ; Arai, T. ; Ramamurthy, V. (2006) Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state Journal of Organic Chemistry, 71 (3). pp. 1055-1059. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0520644
Related URL: http://dx.doi.org/10.1021/jo0520644
Abstract
Volume-demanding cis-trans photoisomerization of the aromatic substituted alkenes 1-3 in the solid state at room temperature and at 50 °C is presented. Alkene 3 did not undergo the cis-trans isomerization in the solid state either at room temperature or at 50 °C. The importance of the presence of void space near the reaction center to facilitate the large volume change during cis-trans photoisomerization is discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55860 |
| Deposited On: | 19 Aug 2011 07:49 |
| Last Modified: | 16 Jul 2012 15:31 |
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