Synthetic studies on morellin. Part 4: Synthesis of 2,2-dimethyl- 12-[3-methylbut-2-enyl]-2H,6H-pyrano[3,2-b]xanthen-6-one

Subba Rao, G. S. R. ; Raghavan, Sadagopan (2001) Synthetic studies on morellin. Part 4: Synthesis of 2,2-dimethyl- 12-[3-methylbut-2-enyl]-2H,6H-pyrano[3,2-b]xanthen-6-one Journal of the Indian Institute of Science, 81 . pp. 393-401. ISSN 0970-4140

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Official URL: http://journal.library.iisc.ernet.in/vol200104/pap...

Abstract

A new synthesis of 2,2-dimethyl-12-[3-methylbut-2-enyl]-2H,6H-pyrano[3,2-b]xanthen-6-one (7) is described from 1,3-dihydroxyxanthone and involved the preparation of a linear dihydropyranoxanthone (26), its conversion into the pyranoxanthone (14) and its prenylated derivative (31) followed by a Claisen rearragement leading to the target substrate (7).

Item Type:Article
Source:Copyright of this article belongs to The Indian Institute of Science (IISc).
Keywords:Morellin; Synthetic Studies; Pyrano[3,2-b]xanthene; Claisen Rearrangement
ID Code:55754
Deposited On:19 Aug 2011 03:36
Last Modified:19 Aug 2011 03:36

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