Selvakumar, Natesan ; Janaki, Seenivasaga N. ; Pramod, Kakumanu ; Subba Rao, G. S. R. (1995) Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels Journal of the Chemical Society, Perkin Transactions 1 (7). pp. 839-846. ISSN 1472-7781
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1995...
Related URL: http://dx.doi.org/10.1039/P19950000839
Abstract
The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 55732 |
| Deposited On: | 19 Aug 2011 03:35 |
| Last Modified: | 19 Aug 2011 03:35 |
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