Synthesis of cis-6,6,9-trimethyl-Δ3,4-octalin-2-one and cis-6,9-dimethyl-6-carbomethoxy-Δ3,4-octalin-2-one: potential de synthons for the construction of pentacyclic triterpenes

Radha Krishna Murthy, A. ; Subba Rao, G. S. R. (1982) Synthesis of cis-6,6,9-trimethyl-Δ3,4-octalin-2-one and cis-6,9-dimethyl-6-carbomethoxy-Δ3,4-octalin-2-one: potential de synthons for the construction of pentacyclic triterpenes Tetrahedron, 38 (22). pp. 3335-3338. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-4020(82)80115-4

Abstract

Synthesis of the bicyclic enones (1 and 2) which are precursors for the rings DE of the pentacyclic triterpenes, β-amyrin and glycyrrhetinic acid has been reported from the readily available 6-methoxy-2-naphthoic acid.

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