John Biju, P. ; Kaliappan, Krishna ; Laxmisha, M. S. ; Subba Rao, G. S. R. (2000) Synthesis based on cyclohexadienes. Part 34. A tandem cationic rearrangement-ene cyclisation route to 2-pupukeanone Journal of the Chemical Society, Perkin Transactions 1 (22). pp. 3714-3718. ISSN 1472-7781
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2000...
Related URL: http://dx.doi.org/10.1039/B003409F
Abstract
A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes, which involves a one-pot cationic skeletal rearrangement and ene cyclisation of a bicyclo[2.2.2]octenone derivative and a cationic rearrangement of a tricyclo[5.3.0.04,8]decane to a [4.3.1.03,7]decane skeleton as the key steps in the synthesis of 2-pupukeanone.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 55584 |
| Deposited On: | 18 Aug 2011 11:26 |
| Last Modified: | 18 Aug 2011 11:26 |
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