Large molecular motions are tolerated in crystals of diamine double salt of trans-chlorocinnamic acids with trans-1,2-diaminocyclohexane

Natarajan, Arunkumar ; Mague, Joel T. ; Venkatesan, K. ; Ramamurthy, V. (2005) Large molecular motions are tolerated in crystals of diamine double salt of trans-chlorocinnamic acids with trans-1,2-diaminocyclohexane Organic Letters, 7 (10). pp. 1895-1898. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol050330u

Related URL: http://dx.doi.org/10.1021/ol050330u

Abstract

Contrary to the general assumption that photoreactions in crystals may not proceed with large molecular motions, a pedal-like motion prompted by electronic excitation is believed to be involved during the β-dimer formation from the crystals of the diamine double salt of trans-2,4-dichlorocinnamic acid and trans-1,2-diaminocyclohexane.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:55490
Deposited On:18 Aug 2011 11:46
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