Kaanumalle, Lakshmi S. ; Gibb, Corinne L. D. ; Gibb, Bruce C. ; Ramamurthy, V. (2004) Controlling photochemistry with distinct hydrophobic nanoenvironments Journal of the American Chemical Society, 126 (44). pp. 14366-14367. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja0450197
Related URL: http://dx.doi.org/10.1021/ja0450197
Abstract
A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 55470 |
Deposited On: | 18 Aug 2011 11:45 |
Last Modified: | 18 Aug 2011 11:45 |
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