Bhanu Prasad, B. A. ; Bisai, Alakesh ; Singh, Vinod K. (2004) Trimethylsilyl cyanide addition to aldimines and its application in the synthesis of (S)-phenylglycine methyl ester Tetrahedron Letters, 45 (52). pp. 9565-9567. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.11.015
Abstract
The addition of TMSCN to a variety of arylaldimines (Strecker reaction) in the presence of LiClO4 or BF3·Et2O in acetonitrile has been studied. The reaction provided the addition products in very high yields. The method has been successfully utilized for the synthesis of (S)-phenylglycine methyl ester.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Imines; TMSCN Addition; α-amino Acid |
| ID Code: | 55383 |
| Deposited On: | 18 Aug 2011 08:39 |
| Last Modified: | 18 Aug 2011 08:39 |
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