Singh, Vinod K. ; DattaGupta, Arpita ; Sekar, G. (1997) Catalytic enantioselective cyclopropanation of olefins using carbenoid chemistry Synthesis, 1997 (2). pp. 137-149. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-1997-1172
Abstract
Use of metal complexes of chiral nonracemic ligands in asymmetric cyclopropanation reactions via homogeneous catalysis is one of the recent developments in synthetic organic chemistry. The extra carbon in the cyclopropane unit from the cyclopropanation of olefins comes from diazo esters or dihalomethanes. In this article we shall discuss the recent aspects of asymmetric intermolecular cyclopropanation reactions where decomposition of these compounds to carbenoid species takes place by organometallic complexes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Enantioselective Cyclopropanation; Chiral Ligands; Carbenoids; Diazoesters; Dihalomethanes |
| ID Code: | 55275 |
| Deposited On: | 18 Aug 2011 08:32 |
| Last Modified: | 18 Aug 2011 08:32 |
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