Carvalho, Chris ; Cullen, William R. ; Fryzuk, Michael D. ; Jacobs, Helen ; James, Brian R. ; Kutney, James P. ; Piotrowska, Krystyna ; Singh, Vinod K. (1989) The chemistry of thujone. Part XIV. Synthesis of biologically active aryl terpenoid analogues Helvetica Chimica Acta, 72 (2). pp. 205-212. ISSN 0018-019X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/hlca.19...
Related URL: http://dx.doi.org/10.1002/hlca.19890720204
Abstract
Employing thujone-derived intermediates, a series of achiral (9a–d; Scheme 1) and chiral (11b and 11d;Scheme 2) terpene analogues related to the biologically active ‘terpenoid’ hybrids have been prepared. The stereochemistry of the key epoxidation reaction was established by correlation of the product 11b with the previously reported alcohol (R)-20 of known absolute configuration (Scheme 3).
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons. |
ID Code: | 55244 |
Deposited On: | 18 Aug 2011 08:25 |
Last Modified: | 18 Aug 2011 08:25 |
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