Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)-Cu(OAc)2·H2O complex

Ginotra, Sandeep K. ; Singh, Vinod K. (2007) Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)-Cu(OAc)2·H2O complex Organic and Biomolecular Chemistry, 5 (24). pp. 3932-3937. ISSN 1477-0520

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2007...

Related URL: http://dx.doi.org/10.1039/B714153J

Abstract

A C2-symmetric diethyl iPr-bis(oxazoline)–Cu(OAc)2·H2O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide β-hydroxy nitroalkanes with high chemical yields (up to 95%) and enantiomeric excesses (up to 97%).

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:55241
Deposited On:18 Aug 2011 08:44
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