The effect of spacer chain length on ion binding to bidentate a,ω-diamines: Contrasting ordering for H+ and Li+ ion affinities

Kiran Kumar, M. ; Srinivasa Rao, J. ; Prabhakar, S. ; Vairamani, M. ; Narahari Sastry, G. (2005) The effect of spacer chain length on ion binding to bidentate a,ω-diamines: Contrasting ordering for H+ and Li+ ion affinities Chemical Communications (11). pp. 1420-1422. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2005...

Related URL: http://dx.doi.org/10.1039/B414426K

Abstract

Electrospray ionisation mass spectrometry studies and quantum chemical calculations indicate that bidentate ligation of Li+ ion to the diamines leads to symmetric bridging and exhibits contrasting relative affinity orderings compared to that of proton for α,ω-diamines.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:55190
Deposited On:18 Aug 2011 12:17
Last Modified:18 Aug 2011 12:17

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