Inversion of configuration of α-trisubstituted(neopentyl) type secondary alcohols

Moriarty, R. M. ; Zhuang, H. ; Penmasta, R. ; Liu, K. ; Awasthi, A. K. ; Tuladhar, S. M. ; Rao, M. S. C. ; Singh, V. K. (1993) Inversion of configuration of α-trisubstituted(neopentyl) type secondary alcohols Tetrahedron Letters, 34 (50). pp. 8029-8032. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)61442-9

Abstract

A variety of hindered α-trisubstituted optically active secondary alcohols has been converted into their enantiomers by treating the corresponding triflates with KNO2 in DMF in the presence of 18-crown-6 at room temperature.

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ID Code:55164
Deposited On:18 Aug 2011 08:25
Last Modified:18 Aug 2011 08:25

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