Raj, Monika ; Parashari, Gopal S. ; Singh, Vinod K. (2009) Highly enantioselective organocatalytic syn- and anti-aldol reactions in aqueous medium Advanced Synthesis & Catalysis, 351 (9). pp. 1284-1288. ISSN 1615-4150
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...
Related URL: http://dx.doi.org/10.1002/adsc.200900122
Abstract
We have synthesized chiral diamines that efficiently catalyze the syn- and anti-aldol reactions in aqueous medium with high diastereo- and enantioselectivities. The product, thus obtained, was further reduced selectively to give syn-configured 1,2,3-triol, an important subunit present in various monosaccharides and natural products such as (+)-boronolide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Aqueous Medium; Mimicking Enzymes; Primary-tertiary Diamines; Quaternary Stereocenters; syn- and anti-aldol Reaction |
| ID Code: | 55159 |
| Deposited On: | 18 Aug 2011 08:48 |
| Last Modified: | 18 Aug 2011 08:48 |
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