Ramana, D. V. ; Vairamani, M. ; Kala, S. (1975) Electron-impact-induced hydrogen migration in organic molecules I- Substituent effects in the mass spectra of pivlanilides Organic Mass Spectrometry, 10 (3). pp. 196-199. ISSN 0030-493X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/oms.121...
Related URL: http://dx.doi.org/10.1002/oms.1210100305
Abstract
Substited pivalanilides give rise to fragments corresponding to anilies on electron-impact, which is due to the migration of a hydrogen atom from the t-butyl group to the nitrogen. The Hammett correlation indicates that the formation of this fragment is favoured by electron-donating groups. The other interesting feature of these spectra is the migration of the aryl group to the t-butyl carbon with the elimination of the neutral ketemine.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons. |
| ID Code: | 55071 |
| Deposited On: | 17 Aug 2011 12:37 |
| Last Modified: | 17 Aug 2011 12:37 |
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