Kundu, Abhijit ; Prabhakar, Sripadi ; Vairamani, M. ; Roy, Sujit (1997) A novel copper (II)/tin (II) reagent for aqueous carbonyl allylation: in situ diagnostics of reactive organometallics in water Organometallics, 16 (22). pp. 4796-4799. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om9704096
Related URL: http://dx.doi.org/10.1021/om9704096
Abstract
A convenient and synthetically attractive protocol for the allylation of aldehydes using stannous chloride and catalytic cupric chloride in dichloromethane/water is described. In situ probing provides indirect (NMR, CV) and direct (MS) evidence for the copper(I)-catalyzed formation of an allyltrihalostannane intermediate in very high concentration in water.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55008 |
| Deposited On: | 18 Aug 2011 12:10 |
| Last Modified: | 19 Jun 2012 08:26 |
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